目录
第一篇 Synthesis and electrochemical properties of two types of highly ordered mesoporous MnO2 ............................................................................................................................................... 11
Lianxia Li, Ping Hua, Xike Tian, Chao Yang, Zhenbang Pi. Electrochimica Acta, 55 (2010): 1682-1686. .............................................................................................................................. 11 1.1 碱性/MnO2电池的优缺点 .............................................................................................. 11 1.2 纳米材料的作用 .............................................................................................................. 11 1.3 MnO2的制备方法............................................................................................................. 11 1.4 SEM、TEM和BET实验描述 ........................................................................................... 22 1.5 电化学性能测试 .............................................................................................................. 22 1.6 CV行为 ............................................................................................................................. 22 1.7 介孔的作用 ...................................................................................................................... 33 第二篇 Heat treated electrolytic manganese dioxide for primary Li/MnO2 batteries: Effect of manganese dioxide properties on electrochemical performance .................................................. 44
Wesley M. Dose, Scott W. Donne. Electrochimica Acta, 105 (2013): 305—313 ..................... 44 2.1 Li/MnO2电池发展及优点 ................................................................................................ 44 2.2 EMD及热处理 .................................................................................................................. 44 2.3 Li/MnO2电池的放电三步骤 ............................................................................................ 55 2.4 EMD物相与电池性能 ...................................................................................................... 55 2.5 EMD阳极沉积过程及机理 .............................................................................................. 55 第三篇 Extraordinarily high pseudocapacitance of metal organic framework derived nanostructured cerium oxide ......................................................................................................... 66
Sandipan Maiti, Atin Pramanik and Sourindra Mahanty. Chem. Commun., 2014, 50, 11717-11720 ........................................................................................................................... 66 3.1电化学赝电容 ................................................................................................................... 66 3.2 CeO2的电容特性及应用 .................................................................................................. 66 3.3 金属有机骨架化合物 ...................................................................................................... 77 3.4 CeO2的充放电过程 .......................................................................................................... 77 3.5 添加K4Fe(CN)6的作用 .................................................................................................... 77 第四篇 Influence of LiMn2O4 modification with CeO2 on electrode performance ....................... 88
Monika Michalska, Bartosz Hamankiewicz, Dominika Zió?kowska, Micha? Krajewski, Ludwika Lipińska, Mariusz Andrzejczuk, Andrzej Czerwiński. Electrochimica Acta 2014, 136: 286–291. ................................................................................................................................................ 88 4.1 LiMn2O4电池的优缺点 ..................................................................................................... 88 4.2 改进方法.......................................................................................................................... 99 4.3 氧化物改进优势 .............................................................................................................. 99 4.4 掺杂CeO2的优点 ............................................................................................................ 99 4.5 充放电行为 ...................................................................................................................... 99 第五篇 CeO2 nanoparticles/graphene nanocomposite-based high performance supercapacitor .................................................................................................................................................... 1010
Yi Wang, Chun Xian Guo, Jiehua Liu, Tao Chen, Hongbin Yang and Chang Ming Li. Dalton Trans., 2011, 40, 6388–6391 ............................................................................................... 1010 5.1 超级电容器的特点及应用 .......................................................................................... 1010 5.2 碳材料在超级电容器材料中应用的优缺点 .............................................................. 1010
5.3 CeO2掺杂的作用 .......................................................................................................... 1111 5.4 计算电容公式 .............................................................................................................. 1111 5.5 EIS特征及解释 ............................................................................................................. 1111 5.6 能量密度计算公式(EIS) .............................................................................................. 1212 第六篇 Influence of the solution pH on the nanostructural, and electrochemical performance of electrolytic manganese dioxide .................................................................................................. 1212
H. Adelkhani, M. Ghaemi. Journal of Alloys and Compounds, 2009, 481: 446-449. .......... 1212 6.1 电沉积MnO2机理及其影响因素 ............................................................................... 1212 6.2 MnO2晶型结构............................................................................................................. 1313 6.3 XRD结构与缺陷 ........................................................................................................... 1313 6.4 温度和pH的影响 ....................................................................................................... 1414 第七篇 Electrochemical performance of Si/CeO2/Polyaniline composites as anode materials for lithium ion batteries .................................................................................................................... 1414
Ying Bai, Yang Tang, Zhihui Wang, Zhe Jia, FengWu, ChuanWu, Gao Liu. Solid State Ionics, 2015, 272: 24-29. ................................................................................................................ 1414 7.1 石墨的优点及理论比电容 .......................................................................................... 1414 7.2 硅的理论比电容及优缺点 .......................................................................................... 1414 第八篇Nano CeO2/activated carbon based composite electrodes for high performance supercapacitor ............................................................................................................................ 1515
L.S. Aravinda, K. UdayaBhat, Badekai Ramachandra Bhat. Materials Letters, 2013, 112: 158–161. ..................................................................................................................................... 1515 8.1 碳载材料...................................................................................................................... 1515 8.2 CeO2电极材料 .............................................................................................................. 1515 8.3 充放电曲线及参数计算公式 ...................................................................................... 1515 8.4 CeO2含量与比电容关系 .............................................................................................. 1515 第九篇 Cerium-based oxide coatings ........................................................................................ 1616
Carlos E. Castano, Matthew J. O’ Keefe, William G. Fahrenholtz. Current Opinion in Solid State and Materials Science, 2015, 19: 69–76. ................................................................... 1616 9.1 铈储量及结构 .............................................................................................................. 1616 9.2 铈氧化物的应用及原因 .............................................................................................. 1616 第十篇 Specific Capacitance and Cyclic Stability of Graphene Based Metal/Metal Oxide Nanocomposites: A Review ........................................................................................................ 1616
Abdul Waheed Anwar, Abdul Majeed, Nadeem Iqbal, Wasi Ullah, Ahmad Shuaib, Usman Ilyas, Fozia Bibi, Hafiz Muhammad Rafique. Journal of Materials Science & Technology, 2015, 31: 699-707. ........................................................................................................................ 1616 10.1 电容器类型与电极材料 ............................................................................................ 1616 10.2 碳材料........................................................................................................................ 1717 10.3 石墨烯........................................................................................................................ 1717 10.4 石墨烯氧化物 ............................................................................................................ 1818 10.5 石墨烯金属或金属氧化物的电容性能 .................................................................... 1919 10.6 电容性能计算公式 .................................................................................................... 1919 10.7 几种材料对比 ............................................................................................................ 2020 第十一篇 Abrupt change with surfactant concentration in the surface morphology of the electrodeposited manganese oxide films for electrochemical capacitors ................................. 2121
Hae-Min Lee, Sung-Woon Cho, Chan-Ju Song, Heung Jung Kang, Bum Jin Kwon, Chang-Koo Kim. Electrochimica Acta, 2015, 160: 50-56. ...................................................................... 2121 11.1超级电容器及机理 ..................................................................................................... 2121 11.2 超级电容器用材料 .................................................................................................... 2222 11.3 锰氧化物优缺点及改良 ............................................................................................ 2222
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