MATERIAL SAFETY DATA SHEET
[1] CHEMICAL PRODUCT / COMPANY IDENTIFICATION - Product name: PS5000 SERIES / SCREEN PRINTING INK - Manufacturer: HANASP CO., LTD.
- Address: UNIT 317, ILSAN UNITECHVILL 1141-2 BAEKSEOK-DONG, INSANDONG-GU GYEONGGI-DO, KOREA
- Phone: +82-31-909-7002 Fax: +82-31-909-7003
[2] COMPOSITION / INFORMATION ON INGREDIENTS - Substance: Mixture
- Product: Screen Printing Ink - Components Cas No. Vinyl chloride resin 25086-48-0 Cyclohexanone 108-94-1 Isophorone 78-59-1 Solvent naphtha 64742-94-5 Glutaric acid dimethyl ester 1119-40-0
Weight 20- 35 15- 25 15- 25 5- 10 5- 10
[3] HAZARDS IDENTIFICATION
- Toxicity information: May have a risk of organic solvent poisoning.
- Physical and chemical hazard: Inflammable Liquid. Remaining gas may cause explosion in contact with air. Flowing or stirring the product may produce a static electricity and it is in danger of ignition and blowup.
- Class name of hazardous chemical –based on Korea regulation: Inflammable Liquid, Acture toxic substance.
Inhalation: causes irritation to respiratory tract. High concentrations can cause central nervous system damage. Death may occur from respiratory failure. Ingestion may cause nausea, vomiting and diarrhea. Skin contact: skin contact causes irritation, redness
Eye contact: may cause irritation, redness and blurred vision. Splashes may cause severe irritation or eye damage.
[4] FIRST AND MEASURES
- Inhalation: Wrap the victim in a blanket, keep in quite and move to fresh air. If breathing is weak, irregular or stopped, administer artificial respiration and arrange the medical treatment by a physician as soon as possible
- Skin contact: Remove all contaminated clothes and shoes immediately. Wash the affected area with plenty of water. Arrange the medical treatment by a physician on injured skin or painful parts.
- Eye contact: Wash off with plenty of water for at least 15 minutes. Arrange the medical treatment. - Ingestion: Do not induce vomiting. Arrange medical inspection immediately.
[5] FIRE FIGHTING MEASURES
- Extinguish media: Powder, Form, Carbon dioxide, dry sand, enforced liquid spray. - Extinguish media not to be used: Water
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- Special fire fighting procedures: Remove the container to a safe place immediately. If difficult to remove, cool down the container and surrounding area with watering. Use the specific extinguish media. Fire fighter should wear proper protective equipment. Keep away from upwind of fire.
[6] ACCIDENTAL RELEASE MEASURES
- Safeguards (Personal): Evacuate personnel near fire. Seal off the area. Shut off all sources of ignition immediately. Fire fighter should wear proper protective equipment. Keep away from upwind of fire. Ventilate the area until all work is completed.
- Environmental precautions: Prevent wastewater form entering watercourses.
- Methods of cleaning up: Soak up the leakage with dry sand and package all materials in a closed container. Flush the area with plenty of water using mild detergent.
[7] HANDLING AND STORAGE Handling:
- Technical measures: implement and equipment should me grounded properly for static protection. Wear conductive work clothes and shoes. Use explosion proof type of electrical equipment and non-sparkling tools.
- Handling precaution: Keep away from fire, spark and heat. Use in the well-ventilated area. Wear proper protective equipment to avoid inhalation and protect eyes and skin. Keep container tightly closed. Minimize vapor exhalation in the air and keep control concentration below standard. Storage:
Put in a closed container after use. Store in a cool, dry and well-ventilated area. Keep away from source of heat such as boiler. Keep away from flammable substances. Separate from oxidizing agent and organic peroxide. Store in a dangerous object warehouse according to fire defense low.
[8] EXPOSURE CONTROL / PERSONAL PROTECTION
- Engineering controls: Use only with adequate ventilation in closed system.
Personal protective equipment: Use gas mask, protective glasses, oil resistance gloves, protective clothes and protective boots.
- Sanitary measures: Change the mask regularly or on as case-by-case basis.
[9] PHYSICAL AND CHEMICAL PROTECTION Physical form:
[ ]Liquid [ ]Vapor [ ]Solid [ ]Powder [X]Paste Color: Each color Odor: solvent odor pH: N/A Boiling point: 154C Flash point: 58C Vapor pressure: --Pa(--C) Density: 1.00-1.60 Soluble in water: Hard Explosion limit(%): Lower: 1.0vol% Upper: 9.5vol%
[10] STABILITY AND REACTIVITY
- Incompatible materials: Dangerous substances and high-pressure gas hazardous decomposition products: Carbon Oxide (CO). - Stability: Stable at room temperature or below. Condition to avoid: Heat
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[11] TOXICOLOGICAL INFORMATION Name Exposure Limit ACGIH (TLV) IARC Others
Isophorone 5ppm 5ppm LD50(Oral) 2330mg/kg Cyclohexanone 25ppm 25ppm LD50(Oral) 1620mg/kg Solvent naphtha N/L N/L LD50(Oral) 2000mg/kg
Information about danger of composition: N/A Information about dangers of products: N/A
[12] ECOLOGICAL INFORMATION
- No information available except being specified as above
[13] DISPOSAL CONSIDERATIONS
Waste ink, opened containers should be asked to dispose with licensed industrial waste treatment company. Don’t wash away the water used for cleaning and of incineration should be disposed of in accordance with government laws and environmental control regulations or asked to dispose with licensed special company. Incase of burning waste inks, ink should be absorbed by diatomaceous earth and then burn in small amount by open type furnace.
[14] TRANSPORTATION INFORMATION
- General: Transport and store according to general caution and instruction in before mentioned comment.
- Land transportation: Transport this product in compliance with the Firefighting Law, Law of industrial safety & hygiene and poisonous & deleterious material control law, if any.
- Maritime transportation: Maritime transportation should be in compliance Law of Maritime Transportation..
- Air transportation: Air transportation should be in compliance with the Aviation Act. - UN Number: 1210
[15] REGULATORY INFORMATION Fire defense law
Occupational health & safety law (ordinance on the prevention of organic solvent poisoning, secondary organic solvent, specific chemical substances)
Road traffic law (regulation on long and massive tunnel, underwater tunnel, express highway) Law of waste disposal and cleaning
[16] OTHER INFORMATION
The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication.
The information given is designed only as a guidance. It is the use’s obligation to determine the condition of safe use of the product.
This safety data sheet is not to be considered a warranty or quality specification.
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兰亭序
永和九年，岁在癸丑，暮春之初，会于会稽山阴之兰亭，修禊事也。群贤毕至，少长咸集。此地有崇山峻岭，茂林修竹；又有清流激湍，映带左右，引以为流觞曲水，列坐其次。虽无丝竹管弦之盛，一觞一咏，亦足以畅叙幽情。是日也，天朗气清，惠风和畅，仰观宇宙之大，俯察品类之盛，所以游目骋怀，足以极视听之娱，信可乐也。
夫人之相与，俯仰一世，或取诸怀抱，晤言一室之内；或因寄所托，放浪形骸之外。虽取舍万殊，静躁不同，当其欣于所遇，暂得于己，快然自足，不知老之将至。及其所之既倦，情随事迁，感慨系之矣。向之所欣，俯仰之间，已为陈迹，犹不能不以之兴怀。况修短随化，终期于尽。古人云：“死生亦大矣。”岂不痛哉！
每览昔人兴感之由，若合一契，未尝不临文嗟悼，不能喻之于怀。固知一死生为虚诞，齐彭殇为妄作。后之视今，亦犹今之视昔。悲夫！故列叙时人，录其所述，虽世殊事异，所以兴怀，其致一也。后之览者，亦将有感于斯文。
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