(3) 8.
乙酰氯
AgNO3 白↓
H2O 乙酸酐 乙酸乙酯
— — I2-NaOH /△ — 黄色↓
HCHCH CHCH CH (2)CHCHCHOH3332C322NaCN HSO24HBr CHOH25[O]+CHCHCH(CH)CHCOOH3332CNCl，少量P2+HO/H2Br (3)CHCHOCHCOOH33EtOH2H+HO/H2NaCNNCCHCOOHHOOCCHCOOH2ClCHCOOH22或CHCHOBrCHCHO32Br① KCN/EtOH0℃,乙醚+②HO/H2HOOCCHCHO 2[O]+HOOCCHCOOH2CHCHO3HHCHO 或 (4)CHCHCHCNCHCHCHCOOH322322NH3稀OH+HO/H2HOCHCHCHOOOCCHCOOH222+HH[O]
9. CHCHCHNH CHCHCHCONH32223222 NaOBr/NaOH
21
10.
CCOOHHOOCCH H/Ni2CHHOOCCHCHCOOH32HOOCCHCCOOH2CH3CHCH2O3CHOH25HOOCCHCCOOCH+CCOOHOHOOCCH25CH3CHO3CHOOCCHCCOOH25 OCHOH25HOOCCHCCOOCHHOOCCHCCOOHO225 + 2CH2CHO2CHOOCCHCCOOH252CH2
11. 12.
第十一章 含氮有机化合物
1. (1) 二甲基乙基胺 (2) N-甲基-N-乙基环己胺 (3) 氢氧化二甲基二乙基铵
(4) 氯化对甲基重氮苯 (5) N,N-二甲基对溴苯胺 (6) 2,3-二甲基-2-氨基丁烷 2.
-
(1) HOCH2CH2NH2 (2) [HOCH2CH2N(CH3)3]+OH
22
(3)HO(5) N NO4)Br(SONHCH23 NHCCH3(6)HNSONH 222 3.
(1) 己胺 > 对甲氧基苯胺 > 苯胺 (2) 戊胺 > 苯胺 > 乙酰苯胺 (3) 甲胺 > 尿素 > 甲酰胺 > 邻苯二甲酰亚胺 CH3 4. (1)(3)(4)(5)N2+ ClNO2+CH3O(2)CH3ONNNH2N(CH3)2SO2NHN CCH3OH + N2 NCH2CH3NH2+-N2Cl+CN -COOH (6)(CH3CH2)2N(CH3)2I (CH3CH2)2N(CH3)2OH
(CH3)2N+C2H5I- + CH2＝CH2
CHCHCHCH3333 5. (1)HNO3Hr/HO222BiHSO24N BrBrNHNONH222 Br (2)Br2Fe,HNO3H2SO4BrH2NiBrNaNO2/HClBr0~5℃NO2SO3HH2SO4NaOH(s)熔融32NH2NH2OHH+N2+ClONa产物
(3)ON2 NHCOCH3HNO,HSO324(CHCO)O2ONNHCOCH23HO/OHNH 20~5℃CNCOClHO/H2NaNO/HCl2ON2ON2CN-KCN+CNCluON223NCOOHO2PCl 6. (1)
C6H5CH2NH2
C6H5CH2NHCH3
不分层
苯磺酰氯 NaOH 23
↓ 可溶于酸
C6H5CH2N(CH3)2
或：
HNO2 C6H5CH2NH2 N2↑
C6H5CH2NHCH3 黄色↓
C6H5CH2N(CH3)2 无明显现象
(2)
苯胺 白↓
Br2 环己基胺 — NaNO2 N2↑ H2O
HCl 环己基甲酰胺 —
—
(3)
苯胺 白↓ —
FeCl3
Br2 显色 苯酚 白↓ H2O
H2O — 环己基胺
7． 水相 CO2 对甲苯酚钠 苯 酚 苯甲醇 NaOH 有机相 苯甲胺 苯甲醇 H2O HCl 苯甲醇 有机相 对甲苯酚 H2O 苯甲胺 水相 苯甲胺 盐酸盐 NaOH H2O CH3NH2CH3OHCH3(C)CH3CHCHCHCH3 8. (A)CH3CHCH2CHCH3CH3NH2HCl(B)CH3CHCH2CHCH3CH3CH3NH3ClOHCH3CHCH2CHCH3HNO2CH3OHCH3CHCH2CHCH3CH3CHCH2CHCH3+ N2CH3CH3CHCHCHCH3CH3CHCH2CHCH3CH3CH3CHCHH2SO41.O3CHCH32.Zn/H2O(CH3)2CHCHO + CH3CHO 24
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