有几家公司小规模生产，但均不成规模。( 2) 聚磷腈合成对原材料纯度和合成环境要求苛刻，生产成本过高，难于工业化。因此寻找合适的合成路线，降低产物成本，促进其实用化以及进一步开发新型聚磷腈功能材料，拓展其应用领域，仍然是今后聚磷腈材料发展的两个重要方向。
参考文献：
[1]张留成, 瞿雄伟, 丁会利, 高分子材料基础, 北京, 化学工业出版社, 2002.
[2] H. R. Allcock, R. L. Kugel, Synthesis of high polymeric alkoxy- and aryloxyphosphonitriles, J. Am. Chem. Soc., 1965, 87 (18): 4216-4217.
[3] H. R. Allcock, R. L. Kugel, Phosphonitrilic compounds. VII. High molecular weight poly(diaminophosphazene), Inorg. Chem., 1966, 5 (10): 1716-1718.
[4] H. R. Allcock, R. L. Kugel, K. J. Valan, Phosphonitrilic compounds. VI. High molecular weight poly(alkoxy- and aryloxyphosphazenes), Inorg. Chem., 1966, 5 (10): 1709-1715. [5] M. K. Potts, G. L. Hagauer, M. S. Sennett, G. Davies, Monomer concentration effects on the kinetics and mechanism of the boron trichloride catalyzed solution polymerization of hexachlorocyclotriphosphazene, Macromolecules, 1989, 22 (11): 4235-4239.
[6] M. S. Sennett, G. L. Hagauer, R. E. Singler, G. Davies, Kinetics and mechanism of borontrichloride (4): 959-964.
[7] C. H. Honeyman, I. Manners, C. T. Morrissey, H. R. Allcock, Ambient temperature synthesis of poly(dichlorophosphazene) with molecular weight control, J. Am. Chem. Soc., 1995, 117 (26): 7035-7036.
[8] H. R. Allcock, C. A. Crane, C. T. Morrissey, I. Manners, Living cationic polymerization of phosphoranimines as an ambient temperature route to polyphosphazenes with controlled molecular weight, Macromolecules, 1996, 29 (24): 7740-7747.
[9]H. R. Allcock, J. M. Nelson, R. Prange, C. A. Crane, C. R. de Denus, Synthesis of telechelic polyphosphazenes via the ambient temperature living cationic polymerization of amino phosphoranimines, Macromolecules, 1999, 32 (18): 5736-5743.
[10]G.D.Halluin,R.DeJaeger, J. P. Chambrette, P. Potin, Synthesis ofpoly(dichorophosphazenes) from Cl3P=NP(O)Cl2, 1. Kinetics and mechanism, Macromolecules, 1992, 25 (4): 1254-1258. [11]G. A. Carriedo, F. J. García Alonso, P. Gómez-Elipe, J. I. Fidalgo, J. L. García álvarez, A. Presa-Soto, A simplified and convenient laboratory-scale preparation of
catalyzed
thermalring-opening
polymerizationof
hexachlorocyclotriphosphazene in 1,2,4-trichlorobenzene solution, Macromolecules, 1986, 19
14N or 15N high molecular weight poly(dichlorophosphazene) directly from PCl5, Chem. Eur. J., 2003, 9 (16): 3833-3836.
[12]宋青, 袁伟忠, 李剑, 唐小真, 一步法合成线性聚二氯磷腈中间体及表征, 上海交通大学学报, 2005, 39 (11): 1824-1827.
[13]H. R. Allcock, D. B. Patterson, T. L. Evans, Synthesis of alkyl and aryl phosphazene high polymers, J. Am. Chem. Soc., 1977, 99 (18): 6095-6096.
[14]H.R. Allcock, T. L. Evans, D. B. Patterson, Reaction of poly(difluorophosphazene) with phenyllithium, Macromolecules, 1980, 13 (2): 201-207.
[15]T. L. Evans, H. R. Allcock, Poly(difluorophosphazene): A new intermediate for the synthesis of poly(organophosphazenes), J. Macromol. Sci. Chem. A, 1981, 16 (1): 409-423.
[16]H. R. Allcock, W. R. Laredo, C. R. de Denus, J. P. Taylor, Ring-opening metathesis polymerization of phosphazene-functionalized norbornenes, Macromolecules, 1999, 32 (23): 7719-7725.
[17]H. R. Allcock, M. B. Mc Intosh, T. J. Hartle, Azido phosphazenes as functionalized intermediates, Inorg. Chem., 1999, 38 (24): 5535-5544.
[18]K. Matyjaszewski, P. J. Miller, J. Pyun, G. Kickelbick, S. Diamanti, Synthesis and characterization of star polymers with varying arm number, length, and composition from organic and hybrid inorganic/organic multifunctional initiators, Macromolecules, 1999, 32 (20): 6526-6535.
[19]张建生 孔庆山 《聚磷腈的合成与应用研究进展》（《青岛大学学报》 2002年12月） [20]York S , Kellam E C ,et al ,A vibrational spectroscopic study oflithiumtriflate in polyphosphazenes with linear oligoethyleneoxyside2chains of different lengths [J]. ElectrochimicaActa ,2001 ,46 ,155321557.
[21]Rabin Bissessur ,David Gallant , Ralf Brüning. New poly [ bis2( methoxyethoxyethoxy ) phosphazene ]2MoS2 nanocomposite[J]. Solid State Ionics ,2003 ,158 ,2052209.
[22]Harry R Allcock ,E Clay Kellam III. The synthesis and applica2tions of novel aryloxy/ oligoethyleneoxy substituted polyphosp2hazenes as solid polymer electrolytes [J]. Solid State Ionics ,2003 , 156 :4012414.
[23]Paulsdorf J , Burjanadze M , Hagelschur K. Ionic conductivity inpolyphosphazene polymer electrolytes prepared by the livingcationic polymerization[J]. Solid State Ionics ,2004 ,169 ,25233. [24]刘承美 ,胡富贞 ,邱进俊. 含吡咯基团导电性聚磷腈的合成及化学氧化聚合[J].高分子材料科学与工程 ,2004 ,20(20) ,89292.
[25]Xu Guo2Xiang ,Lu Qi , Yu Bi2Tao. Inorganic polymer phosp2hazene disulfide as cathode material for rechargeable lithiumbatteries[J ]. Solid State Ionics ,2006 ,177 :3052309.
[26]Harry R Allcock. Recent developments in polyphosphazene ma2terials science[J]. Current Opinion in Solid State and MaterialsScience ,2006 ,10 :231. [27]AllcockH
R
,
Laurencin
C composite
T. nanofibers
Development viaelectrospi
ofbiodegradablepolyphosphazene2nanohydroxyapatite
nning[J]. Appl Micron Nanoscale Mater BiolMed ,Proc Mater Res Soc ,2005 ,845 :291.
[28]Allcock H R , Pucher S R ,Scopelianos A G. Synthesisof poly2organophosphazenes with glycolic acid esterside groups: Proto2types for new bioerodible polymers [J]. Macromolecules ,1994 ,27 : 124.
[29]Lakshmi S , Katti , Laurencin C T. Biodegradable polyphosp2hazenes for drug delivery applications[J]. Advance drug deliveryReview s ,2003 ,55 :467.
[30]Zhang Jianxiang , Li Shuhui , Li Xiaodong ,et al. Morphologymodulation of polymeric assemblies by guest drug molecules:TEM study and compatibility evaluation [J]. Polymer ,2009 ,50 :177821789.
[31]王红霞 ,高长有. 聚(二甘氨酸乙酯) 磷腈合成及其生物相容性[J].高等学校化学学报 ,2007 ,28(10) :1984.
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