Unit 1
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Metals
The use of metals has always ÔÚÈËÀàÉç»áµÄ·¢Õ¹ÖУ¬½ðbeen a key factor in the ÊôµÄÓ¦ÓÃÆð׏ؼüÐÔµÄ×÷Ó᣹¹development of the social ³ÉÎïÖʵĴóÔ¼100ÖÖ»ù±¾ÔªËØÖУ¬systems of man. Of the roughly ´óÔ¼ÓÐÒ»°ëΪ½ðÊô¡£½ðÊôºÍ·Ç½ð100 basic elements of which all ÊôÖ®¼äµÄÇø±ð²»ÊÇÌØ±ðÃ÷ÏÔ¡£×îmatter is composed, about half »ù±¾µÄ¶¨Ò弯ÖÐÔÚÔªËØÔ×Ӽ䴿are classified as metals. The ÔÚµÄÁ¬½ÓÐÎʽºÍÓëÕâЩÔ×ÓÏà¹Ø
distinction between a metal ÁªµÄµç×ÓµÄÄ³Ð©ÌØÐÔ¡£È»¶ø£¬ÔÚ
and a nonmetal is not always ʵ¼ÊÓ¦ÓÃÖУ¬¿ÉÒÔ½«¾ßÓÐÄ³Ð©ÌØ
clear-cut. The most basic ÐÔ¼¯ºÏ½ðÊô¶¨ÒåΪijÖÖÔªËØ¡£
definition centers around the ³ýÁËÉÙÊýÀýÍâ½ðÊôÔÚ³£ÎÂtype of bonding existing ÏÂÊǹÌ̬µÄ¡£ËüÃÇÊÇÈȺ͵çµÄÁ¼between the atoms of the µ¼Ì壬²»Í¸¹â¡£ËüÃÇÍùÍù¾ßÓнÏelement, and around the ¸ßµÄÃܶȡ£Ðí¶à½ðÊô¾ßÓÐÑÓÕ¹ÐÔ£¬
characteristics of certain of Ò²¾ÍÊÇ˵£¬ÔÚ²»±»ÆÆ»µµÄÇé¿öÏÂthe electrons associated with ËüÃǵÄÐÎ×´ÔÚÍâÁ¦µÄ×÷ÓÃÏ¿ÉÒÔ
these atoms. In a more ·¢Éú±ä»¯¡£ÒýÆðÓÀ¾Ã±äÐÎËùÐèµÄpractical way, however, a Á¦ºÍ×îÖÕʹ½ðÊô¶ÏÁÑËùÐèµÄÁ¦Ïàmetal can be defined as an µ±´ó£¬¾¡¹Ü·¢Éú¶ÏÁÑËùÐèµÄÁ¦Ô¶element which has a particular ûÓÐÏñËùÔ¤ÆÚµÄ˺¿ª½ðÊôÔ×ÓËù
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package of properties. ÐèµÄÁ¦ÄÇô´ó¡£
Metals are crystalline when ´ÓÎÒÃǵĹ۵ãÀ´¿´£¬ÔÚËùÓеÄin the solid state and, with ÌØÐÔÖнᾧÐÔÊÇ×îÖØÒªµÄ¡£½á¾§few exceptions (e.g. mercury), ÌåÊÇÕâÑùÒ»Öֽṹ£¬×é³ÉËüµÄÔare
solid
at
ambient ×Ó¶¨Î»ÔÚ¹æÔòµÄÈýάÅÅÁÐÖУ¬·Â
temperatures. They are good conductors
of
heat
and electricity and are opaque to light. They usually have a comparatively high density. Many metals are ductile-that is, their shape can be changed permanently by the application of a force without breaking. The forces required to cause this deformation and those required to break or fracture a metal are comparatively high, although, the fracture forces is not nearly as high as would be expected from simple consideration of the forces ллÐÀÉÍ
·ðλÓÚÈýάÆåÅ̵ķ½¸ñµÄ½ÇÉÏ¡£Ô×Ó¼ä¾àËæ×ÅÔ×Ó´óС³Ê¹æÂÉÐÔ
±ä»¯£¬Ô×Ó¼ä¾àÊǽðÊôµÄÒ»ÖÖÌØÐÔ¡£ÈýάÅÅÁеÄÖáÏß¾ö¶¨Á˾§ÌåÔÚ¿Õ¼äÖеķ½Ïò¡£ÔÚ¹¤³Ìʵ¼ùÖÐÓ¦ÓõĽðÊôÓÉ´óÁ¿µÄ¾§Ìå×é³É£¬ÕâЩ¾§Ìå³ÆÖ®Îª¾§Á£¡£ÔÚ´ó¶àÊýÇé¿öÏ£¬¾§Á£ÔÚ¿Õ¼äÖÐÊÇ×ÔÓÉÅÅÁеġ£ÔÚÔ×Ó·¶Î§ÄÚ£¬¾§Á£Ö®¼äÏ໥½Ó´¥½ôÃܽáºÏ¡£¾§Á£Ö®¼äÁ¬½ÓÇøÓò±»³ÆÎª¾§½ç¡£
¾ø¶Ô´¿¾»µÄ½ðÊô´ÓÀ´Ò²Ã»Óб»Éú²ú³öÀ´¹ý¡£¼´Ê¹¾ø¶Ô´¿¾»µÄ½ðÊô¿ÉÒÔÉú²ú³öÀ´£¬¹¤³ÌʦÃǶÔËüÃÇÒ²²¢²»»áÌØ±ð¸ÐÐËȤ£¬ÒòΪËüÃǺÜÈáÈí¡¢´àÈõ¡£Êµ¼ÊÓ¦ÓÃÖеĽðÊôÍùÍù¶¼°üº¬×ÅÒ»¶¨ÊýÁ¿µÄ
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required to tear apart the Ò»ÖÖ»ò¶àÖÖÍâÀ´½ðÊô»ò·Ç½ðÊôÔªatoms of the metal.
ËØ£¬ÕâЩÍâÀ´ÔªËØ¿ÉÄÜÊÇÓꦵÄ
One of the more significant Ò²¿ÉÄÜÊÇÓÐÒæµÄ»òÕßËüÃǶÔijÖÖof these characteristics from ÌØ¶¨µÄÊôÐÔûÓÐÓ°Ïì¡£Èç¹ûÊÇÓÐour point of view is that of º¦µÄ£¬ÕâЩÍâÀ´ÔªËر»ÈÏΪÊÇÔÓcrystallinity. A crystalline solid is one in which the constituent atoms are located in a regular three-dimensional array as if they were located at the corners of the squares of
a
three-dimensional chessboard. The spacing of the atoms in the array is of the same order as the size of the atoms, the actual spacing being a characteristic of the particular
metal.
The directions of the axes of the array define the orientation of the crystal in space. The metals commonly used in ллÐÀÉÍ
ÖÊ¡£Èç¹ûÊÇÓÐÒæµÄ£¬ËüÃDZ»ÈÏΪÊǺϽðÔªËØ¡£ÔÚ¹¤³Ì²ÄÁÏÖÐÍùÍù±»ÌØÒâµØ¼ÓÈëÒ»¶¨ÊýÁ¿µÄºÏ½ðÔªËØ¡£µÃµ½µÄÎïÖʱ»½Ð×öºÏ½ð¡£ ½ðÊôºÍºÏ½ðÇø±ð²»´ó¡£½ðÊôÕâ¸ö´Ê¿ÉÒÔ°üÀ¨¹¤ÒµÓô¿½ðÊôºÍËüµÄºÏ½ð¡£Ò²Ðí¿ÉÒÔÕâÑù˵£¬ºÏ½ð
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³É·Ö£¬ËüµÄÁ¿¶à´ó¶¼Ó¦¸ÃÔÚ¿ØÖÆ·¶Î§Ö®ÄÚ¡£Òò´Ë£¬µ±ÏëÁ˽â¾ö¶¨½ðÊôºÍºÏ½ðÐÔÖʵÄÒòËØÊ±£¬Ó¦³ä·Ö¿¼ÂÇËüÃǵĻ¯Ñ§×é³É¡£
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engineering practice are ÔÚ50ÖÖ×óÓҵĽðÊôÔªËØÀ
composed of a large number of ¹¤³Ìʵ¼ùÖÐÖ»ÓÐÉÙÊý½ðÊô±»´óÁ¿such crystals, called grains. Éú²úºÍʹÓᣵ½Ä¿Ç°ÎªÖ¹×îÖØÒªIn the most general case, the µÄÊÇÌú£¬ÒÔËüΪ»ù´¡¹¹³ÉÁË´¦´¦crystals of the various grains ¿É¼ûµÄ¸ÖºÍÖýÌú¡££¨Ö÷ÒªÓÉÌúºÍare randomly oriented in ̼¹¹³ÉµÄºÏ½ð£©ËüÃǵÄÖØÁ¿Õ¼Ëùspace.
The
grains
are ÓÐÉú²ú³öÀ´µÄ½ðÊôÖØÁ¿µÄ98%¡£ÔÚ
everywhere in intimate contact ½á¹¹Ó¦Óã¨Ò²¾ÍÊÇ˵£¬¿ÉÒÔ³ÐÊÜwith one another and joined ÔØºÉµÄ½á¹¹£©ÖоÓÓÚÆä´ÎλÖõÄtogether on an atomic scale. ÊÇÂÁ¡¢Í¡¢ÄøºÍîÑ¡£ÔÚËùÓеĽðThe region at which they join Êô²úÁ¿ÖУ¬ÂÁÕ¼0.8£¥£¬ÍÕ¼0.7is known as a grain boundary. £¥£¬Ê£ÏµÄÕ¼0.5£¥¡£Ê£ÏµĽðÊô An absolutely pure metal ÓÃÓÚÏà¶ÔÌØÊâµÄÓÃ;¡£ÀýÈç£¬Äø(i.e. one composed of only one ºÏ½ðÖ÷ÒªÓÃÓÚ¿¹Ä¥ËðºÍÄ͸ßεÄtype of atom) has never been ÓÃ;£¬ÓÉÓÚîѺϽð¾ßÓиßÇ¿¶ÈºÍproduced. Engineers would not µÍÃܶȵÄ×ÛºÏÌØÐÔ£¬îѱ»¹ã·ºÓ¦be particularly interested in ÓÃÓÚº½¿Õ¹¤ÒµÖС£ÄøºÏîÑÓи߳Ésuch a metal even if it were to ±¾ºÍ¸ßÖÊÁ¿µÄʹÓÃÌØÐÔ£¬ÊÂʵÉÏ£¬be produced, because it would ËüÃǸߵijɱ¾ÏÞÖÆÁËËüÃǵÄÓ¦be soft and weak. The metals Óá£
used commercially inevitably ÎÒÃDz»ÄÜÔÚÕâÀïÌÖÂÛÕâЩÉîcontain small amounts of one or °ÂµÄÌØÐÔ¡£ÔںϽð²ÄÁϱ»²ÉÓúÍ
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more foreign elements, either Ó¦ÓÃÓÚ¹¤³Ìʵ¼Ê֮ǰ£¬ÕÆÎÕÆä½á
metallic or nonmetallic. These ¹¹Ç¿¶ÈºÍËüµÄ×ÛºÏÐÔÖʾ͹»ÁË¡£
foreign elements may be ¾ÙÀýÀ´Ëµ£¬Ëü¿ÉÒÔÇ¿¶ÈºÜ¸ß£¬²¢
detrimental, they may be ÇÒÓкõÄÄÍÄ¥ÐÔ£»Ëü¿ÉÒÔ±»ÀýÈç
beneficial, or they may have no ÀÉì¼Ó¹¤£¬»úе¼Ó¹¤£¬»òº¸½ÓµÈinfluence at all on a particular
property.
If disadvantageous, the foreign elements tend to be known as
impurities. If advantageous,
they tend to be known as
alloying elements. Alloying
elements are commonly added
deliberately in substantial
amounts
in
engineering
materials. The result is known as an alloy.
The distinction between the descriptors ¡°metal¡± and ¡°alloy¡± is not clear-cut. The term ¡°metal¡± may be used to
encompass
both
a
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