解：
(1)CH3CH2CH2CH2OH(3)CH3CH2CH2CH2MgBr(5)CH3CH2CH2CH2I(7)CH3CH2CH2CH2CCCH3(9)CH3CH2CH2CH2OC2H5(11)CH3(CH2)3ONO2+ AgBr(2)CH3CH2CHCH2
(4)CH3CH2CH2CH2D(6)CH3CH2CH2CH2CH3(8)CH3CH2CH2CH2NHCH3(10)CH3CH2CH2CH2CN(12)CH3(CH2)3OOCCH3+ AgBr(六) 完成下列反应式：
解：红色括号中为各小题所要求填充的内容。 (1)
OCH3CH3CCH2ICH3CH3COOAgOCCH3CH3CCH2CH3+CH3CH3(主要产物)
CH3OCCH2OCCH3 CH3(次要产物)NaI(2)
BrBrBr丙酮BrI
H3C(3)
H3CNaCNH+H3CCH3CH3CH3HHHDMFHHCNHH
(主要产物)BrDHNaOC2H5C2H5OHCH3O-(次要产物)
(4)
CH3HHCH3H(5)
(R)-CH3CHBrCH2CH3(S)-CH3CHCH2CH3OCH3
(6) HOCH2CH2CH2CH2ClNaOHH2OO
CH3(7) (S)BrCH3CN -COOC2H5H(S)HCNCOOC2H5
C2H5OCOBr(S)NH3CN -COOC2H5NCCBr#SN2NCCOOC2H5CHCH3解释：
HH3CC
HCH3(S)(8) CH3CH2CH2BrCH3CH2CH2NH2
NaNH2CH3CH=CH2
(9)
BrCH3(CH2)2CHCH3NaOHCH3CH2CH=CHCH3 + CH3CH2CH2CH=CH2 + CH3CH2CH2CHCH3OH(10) F(11)
Mg纯醚
BrFMgBr
CH2INaCNCH2CNCH3(CH2)3Li(12)
Ph(13)
HBrCl2h?PhLiBrBrICH3ICH2Cl(A)HCCNaICH2CCH (B)BrHgSO4dil H2SO4Br2h?OICH2CCH3 (C)CHCH3(A)BrNaOHC2H5OH(14)
ClCH2CH3ClClCH=CH2(B)
HBr过氧化物ClCH2CH2Br(C)CH3ONaCH3OHNaCNClCH2CH2CN(D)
Br(15)
ClClNO2ClOCH3NO2(A)Br2FeClOCH3NO2(B)
相关推荐：
loading