100种有机溶剂的极性和其他物理常数列表

pp.408-411 Appendix

Table A-1. Compilation of hundred important organic solvents together with their physical constants, arranged by decreasing E No. (1) (2) (3) (4) (5) (6) (7) (8) (9) Solvent Name Water Formamide 1,2-Ethanediol Methanol N-Methylformamide Diethylene glycol TriethyIene glycol 2-Methoxyethanol Tetraethylene glycol Name in Chinese 水 甲酰胺 乙二醇 甲醇 甲基甲酰胺 双乙二醇 三乙二醇 2-甲氧基乙醇 四乙二醇 甲基乙酰胺 乙醇 氨基乙醇 乙酸 丙醇 苄醇 丁醇 戊醇 异戊醇 异丁醇 异丙醇 2-丁醇 环己醇 碳酸丙二酯 2-戊醇 硝基甲烷 3-戊醇 乙腈 二甲亚砜 苯胺 环丁砜 乙酸酐 二甲基甲酰胺 ET (h) 1 0.799 0.79 0.762 0.722 0.713 0.704 0.667 0.664 0.657 0.654 0.651 0.648 0.617 0.608 0.602 0.568 0.565 0.552 0.546 0.506 0.5 0.491 0.488 0.481 0.463 0.46 0.444 0.42 0.41 0.407 0.404 bp (° C) 100 210.5 197.5 64.5 180-185 245.7 288 124.6 327.3 206.7 78.3 170.95 117.9 97.15 205.45 117.7 138 130.5 107.9 82.2 99.5 161.1 241.7 119 101.2 115.3 81.6 189 184.4 287.3 (dec.) 140 153

(10) N-Methylacetamide (11) Ethanol (12) 2-Aminoethanol (13) Acetic acid (14) 1-Propanol (15) Benzyl alcohol (16) 1-Butanol (17) 1-Pentanol (18) 3-Methyl-1-butanol, Isoamyl alcohol (19) 2-Methyl-1-propanol, Isobutyl alcohol (20) 2-Propanolm) (21) 2-Butanol (22) Cyclohexanol (23) Propylene carbonate (24) 2-Pentanol (25) Nitromethane (26) 3-Pentanol (27) Acetonitrile (28) Dimethylsulfoxide (29) Aniline (30) SulfoIane (31) Acetic anhydride (32) N,N-Dimethyl-formamide

pp.408-411 Appendix

Table A-1. Compilation of hundred important organic solvents together with their physical constants, arranged by decreasing E

(33) N,N-Dimethyl-acetamide (34) Propanenitrile (35) 2-Methyl-2-propanol, t-Butanol (36) 1.3-Dimethyl-imidazolidin-2-one, DMEU (37) 1-Methylpyrrolidin-2-one (38) Acetone (39) 1.3-Dimethyl-2-oxo-hexahydropyrimidine, DMPU (40) 1,2-Diaminoethane (41) Cyanobenzene (42) 1,2-Dichloroethane (43) 2-Butanone (44) Nitrobenzene (45) 2-Methyl-2-butanol, t-Pentyl alcohol (46) 2-Pentanone (47) Tetramethylurea (48) Morpholine (49) Hexamethylphosphoric acid triamide, HMPT (50) 3-Methyl-2-butanone (51) Dichloromethane" (52) Acetophenone (53) Pyridine (54) Methyl acetate (55) Cyclohexanone (56) 4-Methyl-2-pentanone (57) 1,1-Dichloroethane (58) Quinoline (59) 3-Pentanone (60) Chloroform (61) 3,3-Dimethyl-2-butanone (62) Triethylene glycol dimethyl ether (63) 2,4-Dimethyl-3-pentanone (64) Diethylene glycol dimethyl ether (65) 1,2-Dimethoxyethane (66) Ethyl acetate (67) 1,2-Dichlorobenzene (68) 2,6-Dimethyl-4-heptanone (69) Diethylene glycol diethyl ether

二甲基乙酰胺 丙腈 叔丁醇 二甲基乙撑脲 甲基砒咯烷酮 丙酮 二甲基亚丙基脲 乙二胺 腈基苯 1,2-二氯乙烷 丁酮, 甲乙酮 硝基苯 叔戊醇 2-戊酮 四甲基脲 吗啉 六甲基磷酰胺 异戊酮 二氯甲烷 苯乙酮 吡啶 乙酸甲酯 环己酮 4-甲基-2-戊酮 1,1-二氯乙烷 喹啉 3-戊酮 氯仿 3,3-二甲基-2-丁酮 三乙二醇二甲基醚 2,4-二甲基-3-戊酮 双乙二醇二甲基醚 乙二醇二甲基醚 乙酸乙酯 邻二氯苯 2,6-二甲基-4-

庚酮 双乙二醇二乙基醚

0.401 0.401 0.389 0.364 0.355 0.355 0.352 0.349 0.333 0.327 0.327 0.324 0.321 0.321 0.318 0.318 0.315 0.315 0.309 0.306 0.302 0.287 0.281 0.269 0.269 0.269 0.265 0.259 0.256 0.253 0.247 0.244 0.231 0.228 0.225 0.225 0.21

166.1 97.35 82.3 225.5 202 56.1 230 116.9 191.1 83.5 79.6 210.8 102 102.3 175.2 128.9 233 94.2 39.6 202 115.25 56.9 155.65 117.4 573 237.1 102 61.2 106.3 216 125.25 159.8 (dec.) 84.5 77.1 180.5 168.2 188.9

(70) Tetrahydrofuran (71) Methoxybenzene (72) Diethyl carbonate (73) Fluorobenzene (74) 1,1-Dichloroethene (75) Chlorobenzene (76) Bromobenzene (77) Ethoxybenzene (78) lodobenzene (79) 1,1,1-Trichloroethane (80) 1,4-Dioxane (81) Trichloroethene (82) t-Butyl methyl ether (83) Piperidine (84) Diethylamine (85) Diphenyl ether (86) Diethylether (87) Benzene (88) Di-n-propyl ether (89) Toluene (90) 1,4-Dimethylbenzene (91) Di-n-butyl ether (92) Carbon disulfide (93) Tetrachloromethane (94) Triethylamine (95) Tri-n-butylamine (96) cis-Decahydro-naphthaline (97) n-Heptane (98) n-Hexane (99) n-Pentane (100) Cyclohexane

四氢呋喃 苯甲醚 碳酸二乙酯 氟苯 1,1-二氯乙烯 氯苯 溴苯 苯乙醚 碘苯 1,1,1-三氯乙烷 二噁烷 三氯乙烯 叔丁基甲醚 哌啶 二乙基胺 二苯醚 乙醚 苯 二丙醚 甲苯 对二甲苯 二丁醚 二硫化碳 四氯甲烷 三乙基胺 三丁基胺 顺十氢萘 正庚烷 正己烷 正戊烷 环己烷

0.207 0.198 0.194 194 0.194 0.188 0.182 0.182 0.17 0.17 0.164 0.16 0.148 0.148 0.145 0.142 0.117 0.111 0.102 0.099 0.074 0.071 0.065 0.052 0.043 0.043 0.015 0.012 0.009 0.009 0.006

66 153.6 126.8 84.7 31.6 131.7 155.9 169.8 188.3 74.1 101.3 87.2 55.2 106.2 55.55 258.1 344 801 90.1 110.6 138.4 140.3 46.2 76.6 88.9 214 195.8 98.4 68.7 36.1 80.7

a The physical constants were taken from the following references: (1) R. C. Weast and M. J. Astle: CRC Handbook of Data o c Melting point. d Boiling point at 1013 mbar. e Relative permittivity (dielectric constant) for the pure liquid at 25° C unless followed by another temperature in parentheses.

b C. Reichardt and E. Harbusch-G° rnert. Liebigs Ann. Chem 1983,721; C. Laurence, P. Nicolet. M. Lucon, and C. Reichardt, B

a The physical constants were taken from the following references: (1) R. C. Weast and M. J. Astle: CRC Ha

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